Experimental verification of minima in excited long-range Rydberg states of Rb2.

نویسندگان

  • Chris H Greene
  • Edward L Hamilton
  • Heather Crowell
  • Cedomil Vadla
  • Kay Niemax
چکیده

Recent theoretical studies with alkali atoms A* excited to high Rydberg states predicted the existence of ultra-long-range molecular bound states. Such excited dimers have large electric dipole moments which, in combination with their long radiative lifetimes, make them excellent candidates for manipulation in applications. This Letter reports on experimental investigations of the self-broadening of Rb principal series lines, which revealed multiple satellites in the line wings. The positions of the satellites agree quantitatively with theoretically predicted minima in the excited long-range Rydberg states of Rb2.

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

ar X iv : p hy si cs / 0 60 92 20 v 1 2 5 Se p 20 06 Experimental verification of minima in excited long - range Rydberg states of Rb 2 Chris

Chris H. Greene, Edward L. Hamilton, Heather Crowell, Cedomil Vadla, and Kay Niemax Department of Physics and JILA, University of Colorado, Boulder, CO 80309-0440 Department of Chemistry, Northwestern University, Evanston, IL 60208-3113 Department of Chemistry and JILA, University of Colorado, Boulder, CO 80309-0440 Institute of Physics, Zagreb, Croatia and ISAS – Institute for Analytical Scien...

متن کامل

Ultracold Atoms in Optical Lattices: Quantum Simulation of the Fermi-Hubbard Model

We observe long-range “trilobite-like” states of ultracold 85Rb2 molecules in which a novel form of chemical bonding occurs: an ultracold ground state atom is bound by the attraction of the Rydberg electron, with its Rydberg electronic wavefunction in np Rydberg atomic levels with n = 7-12 [1]. Unlike earlier work by others at much higher n formed by photoassociation, our observations involve b...

متن کامل

Ultracold Chemical Reactions of a Single Rydberg Atom in a Dense Gas

Within a dense environment (ρ ≈ 10 atoms=cm) at ultracold temperatures (T < 1 μK), a single atom excited to a Rydberg state acts as a reaction center for surrounding neutral atoms. At these temperatures, almost all neutral atoms within the Rydberg orbit are bound to the Rydberg core and interact with the Rydberg atom. We have studied the reaction rate and products for nS Rb Rydberg states, and ...

متن کامل

The role of excited Rydberg States in electron transfer dissociation.

Ab initio electronic structure methods are used to estimate the cross sections for electron transfer from donor anions having electron binding energies ranging from 0.001 to 0.6 eV to each of three sites in a model disulfide-linked molecular cation. The three sites are (1) the S-S sigma(*) orbital to which electron attachment is rendered exothermic by Coulomb stabilization from the nearby posit...

متن کامل

Ab initio calculations on the ground and excited states of BeOH and MgOH

Ab initio configuration interaction calculations have been carried out on the ground and excited electronic states of the BeOH and MgOH molecules as well as of the cations BeOH and MgOH, for linear and bent geometries. The excited states of the above molecules have not previously been calculated and experimental information exists only for the A – X system in MgOH and MgOD. The present results ...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

عنوان ژورنال:
  • Physical review letters

دوره 97 23  شماره 

صفحات  -

تاریخ انتشار 2006